Tracklist Hide Credits
| 1-1 | –Morton Stevens | First Season Main Title, RevisedWritten-By – Goldsmith* |
| Jerry Goldsmith Medley: The Deadly Games Affair | ||
| 1-2a | –Jerry Goldsmith | Headquarters |
| The Vulcan Affair | ||
| 1-2b | –Jerry Goldsmith | Plane To Washington |
| The King Of Knaves Affair | ||
| 1-2c | –Jerry Goldsmith | New Assignment |
| The Vulcan Affair | ||
| 1-2d | –Jerry Goldsmith | Solo Speeds |
| 1-2e | –Jerry Goldsmith | Bloody Solo |
| The King Of Knaves Affair | ||
| 1-2f | –Jerry Goldsmith | She's A Notary |
| 1-2g | –Jerry Goldsmith | Writer-Director Card |
| The Quadripartite Affair | ||
| 1-3 | –Walter Scharf | The Mountains |
| The Double Affair Suite No. 2 | ||
| 1-4a | –Morton Stevens | Robotitis |
| 1-4b | –Morton Stevens | Dual Solo |
| 1-4c | –Morton Stevens | Devious Path |
| 1-4d | –Morton Stevens | Namana's End |
| 1-5 | –Jerry Goldsmith | Belly Laughs |
| The Finny Foot Affair | ||
| 1-6a | –Morton Stevens | Incendiary Affair |
| 1-6b | –Morton Stevens | Air-Ground Duel |
| 1-6c | –Morton Stevens | Smorgasboard |
| The Fiddlesticks Affair Suite No. 2 | ||
| 1-7a | –Lalo Schifrin | Electrostatic Field |
| 1-7b | –Lalo Schifrin | Electro-Dice |
| The Yellow Scarf Affair | ||
| 1-8a | –Morton Stevens | Goddess Kali |
| 1-8b | –Morton Stevens | Sniper Strangled |
| 1-9 | –Jerry Goldsmith | Meet Mr. Solo |
| 1-10 | –Morton Stevens | The Spy With My Face |
| The Discotheque Affair Suite No. 2 | ||
| 1-11a | –Gerald Fried | Time Bomb |
| 1-11b | –Gerald Fried | Paint Job |
| 1-11c | –Gerald Fried | The Turncoat |
| 1-11d | –Gerald Fried | Let There Be Light |
| 1-11e | –Gerald Fried | The Carving Of Carver |
| 1-11f | –Gerald Fried | The Kiss Goodbye |
| The Nowhere Affair | ||
| 1-12a | –Robert Drasnin | Warm To Mara |
| 1-12b | –Robert Drasnin | Somewhere |
| 1-13 | –Gerald Fried | U.N.C.L.E. A Go Go |
| The Bat Cave Affair | ||
| 1-14a | –Gerald Fried | Olé |
| 1-14b | –Gerald Fried | The Bottom |
| 1-14c | –Gerald Fried | Zark |
| 1-14d | –Gerald Fried | Motorcycle |
| 1-14e | –Gerald Fried | Zark's Friends |
| 1-14f | –Gerald Fried | Grampaw |
| One Of Our Spies Is Missing | ||
| 1-15a | –Gerald Fried | Go-Go In Soho |
| 1-15b | –Gerald Fried | Thrush-Cycle |
| The Monks Of St. Thomas Affair Suite No. 2 | ||
| 1-16a | –Gerald Fried | Brother John |
| 1-16b | –Gerald Fried | Brother John #2 |
| 1-16c | –Gerald Fried | Scenery |
| 1-16d | –Gerald Fried | Baggage |
| 1-16e | –Gerald Fried | Fight |
| 1-16f | –Gerald Fried | The Hook |
| 1-16g | –Gerald Fried | Left At The Post |
| The Spy In The Green Hat | ||
| 1-17 | –Gerald Fried / Robert Armbruster | Main TitleWritten-By – Goldsmith* |
| Gerald Fried Medley: The Foreign Legion Affair | ||
| 1-18a | –Gerald Fried | Illya, Boy Arab |
| The Apple A Day Affair | ||
| 1-18b | –Gerald Fried | Apple A Day Affair |
| 1-18c | –Gerald Fried | Hillbilly Country |
| The Her Master's Voice Affair | ||
| 1-18d | –Gerald Fried | Chess |
| The It's All Greek To Me Affair | ||
| 1-18e | –Gerald Fried | Athens |
| The Hot Number Affair | ||
| 1-18f | –Gerald Fried | Hot Number Affair |
| 1-18g | –Gerald Fried | Fink Genius |
| The Sort Of Do-It-Youself Dreadful Affair | ||
| 1-18h | –Gerald Fried | The Truth |
| The My Friend The Gorilla Affair | ||
| 1-18i | –Gerald Fried | Flat Tire |
| 1-18j | –Gerald Fried | The Indian Affairs Affair |
| 1-18k | –Gerald Fried | Indian Uprising |
| The Karate Killers | ||
| 1-19a | –Gerald Fried | The Karate Killers |
| 1-19b | –Gerald Fried | Karate And Stick Game |
| Richard Shores Medley: The Summit-Five Affair | ||
| 1-20a | –Richard Shores | To Helga |
| 1-20b | –Richard Shores | Security Leak |
| 1-20c | –Richard Shores | Thirty Seconds |
| The "J" For Judas Affair | ||
| 1-20d | –Richard Shores | Like Crazy |
| 1-20e | –Richard Shores | Headquarters |
| 1-20f | –Richard Shores | Take Cover |
| 1-20g | –Richard Shores | They Got Him |
| 2-1 | –Dave Grusin | The Girl From U.N.C.L.E. Main TitleWritten-By – Goldsmith* |
| The Dog-Gone Affair | ||
| 2-2a | –Dave Grusin | Dog-Gone Blues |
| 2-2b | –Dave Grusin | The One That Got Away |
| 2-2c | –Dave Grusin | Thrush Convention |
| 2-2d | –Dave Grusin | Last Fight |
| 2-2e | –Dave Grusin | Greek Reprise |
| The Prisoner Of Zalamar Affair | ||
| 2-3a | –Richard Shores | Bomb Scare |
| 2-3b | –Richard Shores | Sneaky Search |
| 2-3c | –Richard Shores | Crazy Confusion |
| 2-3d | –Richard Shores | April |
| The Mother Muffin Affair | ||
| 2-4a | –Dave Grusin | Rodney Rigid |
| 2-4b | –Dave Grusin | Out Of The Fire |
| 2-4c | –Dave Grusin | Leave The Driving To Us |
| 2-4d | –Dave Grusin | Questionable Future |
| 2-4e | –Dave Grusin | Shall We Gather At The Boat Dock? |
| 2-4f | –Dave Grusin | Tearful Farewell |
| 2-4g | –Dave Grusin | Anna Maria Who? |
| The Mata Hari Affair | ||
| 2-5a | –Dave Grusin | Recuperating |
| 2-5b | –Dave Grusin | Rolaflex Special |
| 2-5c | –Dave Grusin | Cockney Soul |
| 2-5d | –Dave Grusin | The Heaviest |
| 2-5e | –Dave Grusin | Recovery And Escape |
| 2-5f | –Dave Grusin | Dance Of The Veil |
| 2-5g | –Dave Grusin | Henny Waverly |
| 2-5h | –Dave Grusin | Writer/Director Card |
| The Montori Device Affair | ||
| 2-6a | –Richard Shores | Raid |
| 2-6b | –Richard Shores | Watched |
| 2-6c | –Richard Shores | Mark's Trouble |
| 2-6d | –Richard Shores | Red Handed |
| 2-6e | –Richard Shores | Lost Fight |
| The Horns-Of-The Dilemma Affair | ||
| 2-7 | –Jack Marshall | The Horns Of The Dilemma |
| 2-8 | –Dave Grusin | The Girl From U.N.C.L.E. End TitleWritten-By – Goldsmith* |
| The Man From U.N.C.L.E.: The Deadly Quest Affair | ||
| Teaser | ||
| 2-9a | –Jerry Goldsmith | Solo Strikes Again |
| 2-9b | –Jerry Goldsmith | Dead Men Don't Talk |
| 2-9c | –Jerry Goldsmith | The Grand Tour |
| 2-9d | –Jerry Goldsmith | Hot Money |
| Act I | ||
| 2-10a | –Jerry Goldsmith | Man In A Can |
| 2-10b | –Jerry Goldsmith | Night School |
| 2-10c | –Jerry Goldsmith | Auction Tonight |
| 2-10d | –Jerry Goldsmith | Sweet Smell Of Success |
| Act II | ||
| 2-11a | –Jerry Goldsmith | President Gets A Mickey |
| 2-11b | –Jerry Goldsmith | Research On Vulcan |
| 2-11c | –Jerry Goldsmith | The Blowout |
| 2-11d | –Jerry Goldsmith | A Friend In Need |
| 2-11e | –Jerry Goldsmith | The Intruder |
| 2-11f | –Jerry Goldsmith | Win By Default |
| 2-11g | –Jerry Goldsmith | The Big Blow |
| Act III | ||
| 2-12a | –Jerry Goldsmith | Confined Again |
| 2-12b | –Jerry Goldsmith | At Knife Point |
| 2-12c | –Jerry Goldsmith | Breakout |
| Act IV | ||
| 2-13a | –Jerry Goldsmith | Late Visitor |
| 2-13b | –Jerry Goldsmith | The Raid |
| 2-13c | –Jerry Goldsmith | The Unwilling Guests |
| 2-13d | –Jerry Goldsmith | Have A Little Pain |
| 2-13e | –Jerry Goldsmith | Meet Mr. Solo |
